KMS Nanjing Institute of Geology and Palaeonotology,CAS
Novel symmetrical coralloid Cu 3D superstructures: Solid-state synthesis from a Cu-carboxylate MOF and their in-situ thermal conversion | |
Chen, Lingyun1; Shen, Yongming2; Bai, Junfeng2; Wang, Chunzhao (王春朝)3 | |
2009-08-01 | |
发表期刊 | JOURNAL OF SOLID STATE CHEMISTRY |
ISSN | 0022-4596 |
卷号 | 182期号:8页码:2298-2306 |
摘要 | We describe here a one-step solid-state process for the synthesis of metal three-dimensional (3D) superstructures from a metal-organic framework (MOF). Novel symmetrical coralloid Cu 3D superstructures with surface interspersed with clusters of Cu nanoparticles were successfully synthesized by thermolysis of the [Cu(3)(btc)(2)] (btc = benzene-1,3,5-tricarboxylato) MOF in a one-end closed horizontal tube furnace (OCTF). The obtained products were characterized by TGA. FT-IR, XRD, EDX, SEM, TEM, HRTEM and SAED. Different reaction conditions were discussed. Furthermore, the synthesized Cu samples were converted into CuO microstructures by in-situ calcination in the air. In addition, the possible formation mechanism was also proposed. This method is a simple and facile route, which builds a direct linkage between meta I-carboxylate MOF crystals and metal nano- or microstructures and also opens a new application field of MOF's. Crown Copyright (C) 2008 Published by Elsevier Inc. All rights reserved. |
关键词 | Metal-organic Framework Solid-state Thermolysis Superstructure Cu Cuo |
DOI | 10.1016/j.jssc.2009.06.007 |
语种 | 英语 |
关键词[WOS] | Metal-organic Framework ; Coordination Polymers ; Catalytic-properties ; Copper Nanowires ; Route ; Nanoparticles ; Transformation ; Nanocrystals ; Thermolysis ; Nanotubes |
资助项目 | National Natural Science Foundation of China[20771058] ; Major State Basic Research Development Program[2006CB86104] ; NSFC[20721002] |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
WOS记录号 | WOS:000269066400045 |
项目资助者 | National Natural Science Foundation of China ; Major State Basic Research Development Program ; NSFC |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
文献类型 | 期刊论文 |
条目标识符 | http://ir.nigpas.ac.cn/handle/332004/250 |
专题 | 中国科学院南京地质古生物研究所 |
通讯作者 | Chen, Lingyun |
作者单位 | 1.Chongqing Univ, Coll Chem & Chem Engn, Chongqing 400030, Peoples R China 2.Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China 3.Chinese Acad, Nanjing Inst Geol & Palaeontol, State Key Lab Palaeobiol & Stratig, Nanjing 210008, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Lingyun,Shen, Yongming,Bai, Junfeng,et al. Novel symmetrical coralloid Cu 3D superstructures: Solid-state synthesis from a Cu-carboxylate MOF and their in-situ thermal conversion[J]. JOURNAL OF SOLID STATE CHEMISTRY,2009,182(8):2298-2306. |
APA | Chen, Lingyun,Shen, Yongming,Bai, Junfeng,&Wang, Chunzhao .(2009).Novel symmetrical coralloid Cu 3D superstructures: Solid-state synthesis from a Cu-carboxylate MOF and their in-situ thermal conversion.JOURNAL OF SOLID STATE CHEMISTRY,182(8),2298-2306. |
MLA | Chen, Lingyun,et al."Novel symmetrical coralloid Cu 3D superstructures: Solid-state synthesis from a Cu-carboxylate MOF and their in-situ thermal conversion".JOURNAL OF SOLID STATE CHEMISTRY 182.8(2009):2298-2306. |
条目包含的文件 | ||||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论